Profile         研究内容         所属学会         学歴         職歴         受賞歴         研究業績        更新日:2017/07/29 







辻 悦司 (Etsushi TSUJI)

E. Tsuji       講師、博士(理学)

            E-mail: e-tsuji(at)chem.tottori-u.ac.jp
                             ((at)を@に変えて下さい)

            TEL/FAX: 0857-31-5257(内線4266)

             居室: 工学部 4304室

             担当授業: (学部)   無機化学Ⅱ、物理化学Ⅲ、無機化学演習、応用化学実験Ⅱ、応用化学実験Ⅲ
                                (大学院) 表面化学特論 


【 研究内容 】

   2016~
study3-1-1
   水素と酸素からエネルギーを取り出し、排出するのは水だけである燃料電池。最近では家庭用のエネファーム
   や、トヨタから販売が開始された燃料電池車ミライなど、ますます注目が集まっています。

   しかしその一方で肝心な水素は、石油や天然ガスなどの水蒸気改質により生成しています。これで本当にクリ
   ーンと言えるのでしょうか?そこで本当の意味でのクリーン水素を実現できるように光を当てることで水を分解し、
   水素と酸素を生成できる複合型光触媒の開発を進めています。
  study3-1-2

study3-2-1
   衣料、医薬品、ペットボトルなど我々の身の回りにある化学製品。これらは原油を原料としており、もはや
   化学製品なしでは我々の生活は成り立ちません。

   しかしその一方で原油は枯渇が危ぶまれており、新たな炭素資源の探索が必要です。これに対しメタン
   主成分とする天然ガスは、近年、その生産量は増加していますが、燃料としての利用がほとんどです。
   もしも天然ガスから化学製品が作れたら…そんな新しい触媒開発を進めています。
  study3-2-2

study3-3-1
   代表的な固体酸触媒であるゼオライト。我々の豊かな生活を送るうえで、もはや必要不可欠なものとなって
   います。

   様々な用途に応じて、様々なゼオライトが使い分けられています。本研究では、ゼオライトとナノ構造体を
   組み合わせる
ことで、触媒1つで様々な用途に利用できる、これまでなかった触媒の構築を目指しています。
  study3-3-2

   これまでの研究
    2011~2015
  (助教 in 北海道大学)
            1. アノード酸化法による機能性酸化物メソ・マクロポーラス薄膜の合成とエネルギー変換分野への応用
            2. 亜鉛空気二次電池への利用を目指した新規空気極用遷移金属酸化物触媒の開発

    2005~2011  (学生 in 大阪大学)
            1. 酸化物触媒における原子レベル構造規制表面が光酸素発生反応に与える影響の解明
            2. 光触媒の表面構造規制によるバンド構造制御


【 所属学会 】

日本化学会電気化学会表面科学会表面技術協会腐食防食学会ゼオライト学会触媒学会石油学会




【 学歴 】

2006年3月 大阪大学基礎工学部化学応用科学科卒業

2008年3月 大阪大学大学院基礎工学研究科博士前期課程物質創成専攻修了

2011年3月 大阪大学大学院基礎工学研究科博士後期課程物質創成専攻修了
                       (うち2009年1月-3月 University of Guelph (Canada, Prof. J. Lipkowski))


【 職歴 】

2008年4月 日本学術振興会 特別研究員(DC1)

2011年4月 北海道大学大学院工学研究院物質化学部門 助教

                       (うち2012年7月-9月 The University of Manchester (UK, Prof. G.E. Thompson)  博士研究員)

2015年6月 北海道大学大学院工学研究院応用化学部門 助教(改組)

2015年10月 鳥取大学大学院工学研究科化学・生物応用工学専攻 講師
                       (うち2015年10月-2016年3月 北海道大学大学院工学研究院応用化学部門 招聘教員 兼任)

                       (現在に至る)


【 受賞歴 】

2006年3月 大阪大学基礎工学部・基礎工学部賞

2008年3月 大阪大学基礎工学研究科・物質創成専攻賞

2014年8月 10th International Symposium on Electrochemical Micro & Nanosystem Technologies, Distinguished Poster Award
                       "Nanostructural Control and Photocatalytic Application of Anodic TiO2 Nanochannel Films"


2016年3月 電気化学会進歩賞(佐野賞)
                       「原子・ナノスケール構造に着目した機能性金属酸化物の創製とクリーンエネルギー変換技術への応用」


2016年5月 第10回新素材共同研究開発センター共同利用研究課題最優秀賞


【 研究業績 】

[ 査読付論文 ]

[46] Low temperature oxygen storages of YCr1-xPxO4-δ mediated by local condensation around oxygen-deficient orthochromite(IV)
Y. Aoki, K. Kuroda, S. Hinokuma, C. Kura, C. Zhu, H. Habazaki, M. Wakeshima, Y. Hinatsu, E. Tsuji and A. Nakao J. Am. Chem. Soc., 2017, in press.

[45] Facile Preparation of Self-healing Superhydrophobic CeO2 Surface by Electrochemical Processes
K. Nakayama, T. Hiraga, C. Zhu, E. Tsuji, Y. Aoki and H. Habazaki Appl. Surf. Sci., 2017, 423, 968-976.

[44] Influence of Acidic Property on Catalytic Activity and Selectivity in Dehydration of Glycerol
S. Suganuma, T. Hisazumi, K. Taruya, E. Tsuji and N. Katada Chemistry Select, 2017, 2, 5524-5531.

[43] Brownmillerite-type Ca2FeCoO5 as a practicable oxygen evolution reaction catalyst
E. Tsuji, T. Motohashi, H. Noda, D. Kowalski, Y. Aoki, H. Tanida, J. Niikura, Y. Koyama, M. Mori, H. Arai, T. Ioroi, N. Fujiwara, Y. Uchimoto, Z. Ogumi and H. Habazaki Chemsuschem, 2017, 10, 2864-2868.
【Front Cover採用】


[42] Highly Increased Capacitance and Thermal Stability of Anodic Oxide Films on Oxygen-incorporated Zr-Ti Alloy
H. Habazaki, K. Kobayashi, E. Tsuji, C. Zhu, Y. Aoki and S. Nagata J. Solid State Electrochem., 2017, 21, 1-10.

[41] Anodic Films Obtained on Ti6Al4V in Aluminate Solutions by Spark Anodizing: Effect of OH and WO4-2 Additions on the Tribological Properties
D. Quintero, M.A Gómez, Castaño, E. Tsuji, Y. Aoki, F. Echeverría and H. Habazaki Surf. Coatings Technol., 2017, 310, 180-189.

[40] Growth of barrier type anodic film on magnesium in ethylene glycol-water mixed electrolytes containing fluoride and phosphate
K. Shahzad, C. Zhu, E. Tsuji, Y. Aoki, S. Nagata and H. Habazaki Materials Transactions 2016, 57, 1552-1559.

[39] Control of Atomic or Nano-Scale Structure of Functional Metal Oxides for Clean Energy Conversion Systems
E. Tsuji Electrochemistry 2016, 84, 667-673.

[38] Formation of Porous Anodic Films on Carbon Steels and Their Application to Corrosion Protection Composite Coatings with Polypyrrole
Y. Konno,A. Farag, E. Tsuji, Y. Aoki and H. Habazaki J. Electrochem. Soc. 2016, 163, C386-393.

[37] Electrochemical Impedance Spectroscopy of High-Efficiency Hydrogen Membrane Fuel Cells Based on Sputter-Deposited BaCe0.8Y0.2O3−δ Thin Films
Y. Aoki, S. Kobayashi, E. Tsuji, H. Habazaki and M. Martin RSC Advances 2016, 6, 8964-8970.

[36] Fabrication of Resistive Switching Gallium Oxide Thin Film with Tailoring Gallium Valence State and Oxygen Deficiency by rf Cosputtering Process
C. Kura, Y. Aoki, E. Tsuji, H. Habazaki and M. Martin RSC Advances 2016, 6, 8964-8970.

[35] Control of Surface Wettability of Aluminum Mesh with Hierarchical Surface Morphology by Monolayer Coating: from Superoleophobic to Superhydrophilic
K. Nakayama, E. Tsuji, Y. Aoki, S. Paark and H. Habazaki J. Phys. Chem. C 2015, 120, 15684-15690.

[34] Characterization of Corrosion-resistant, Nanometer-thick, Layer-by-layer Aluminosilicate Coatings Prepared on Stainless Steel
H. Habazaki, T. Kimura, Y. Aoki, E. Tsuji, Y. Yano, K. Shimizu and A.W. Hassel Electrochim. Acta 2016, 201, 311-319.

[33] GDOES Depth Profile Analysis of Interfacial Enrichment of Copper during Anodizing of Al-Cu Alloy
H. Habazaki, M. Uemura, K. Fushimi, E. Tsuji, Y. Aoki and S. Nagata Journal of The Surface Finishing Society Japan 2015, 66, 670-672.

[32] Redox-induced Proton Insertion and Desertion of Zircon-type Neodymium Chromate(V)
Y. Aoki, K. Kuroda, E. Tsuji and H. Habazaki Solid State Ionics 2015, in press.

[31] Growth of Barrier-type Anodic Films on Magnesium in Ethylene Glycol Electrolytes Containing Fluoride and Water
H. Habazaki, F. Kataoka, K. Shahzad, E. Tsuji, Y. Aoki, S. Nagata, P. Skeldon and G.E. Thompson Electrochim. Acta 2015, 179, 402-410.

[30] Corrosion Protection of Iron Using Porous Anodic Oxide/Conducting Polymer Composite Coatings
Y. Konno, E. Tsuji, Y. Aoki, T. Ohtsuka and H Habazaki Faraday Discuss. 2015, 180, 479-493.

[29] Highly Durable Platelet Carbon Nanofiber-Supported Platinum Catalysts for the Oxygen Reduction Reaction
E. Tsuji, T. Yamasaki, Y. Aoki, S.G. Park, K. Shimizu and H. Habazaki Carbon 2015, 87, 1-9.

[28] Formation and Field-assisted Dissolution of Anodic Films on Iron in Fluoride-containing Organic Electrolyte
K. Shahzad, E. Tsuji, Y. Aoki, S. Nagata and H. Habazaki Electrochim. Acta 2015, 151, 363-369.

[27] Electrochemical Analysis of Hydrogen Membrane Fuel Cells with Amorphous Zirconium Phosphate Thin Film Electrolyte
R. Nonaka, Y. Aoki, E. Tsuji and H. Habazaki Electrochemistry 2014, 82, 859-864.

[26] Mixed Proton Electron Conductivity of Calcium Chromate(V) Apatite
Y. Aoki, K. Kikutani, E. Tsuji and H. Habazaki Electrochem. Lett. 2014, 3, F61-F64.

[25] Fabrication of Superoleophobic Hierarchical Surfaces for Low-Surface-Tension Liquids
H. Habazaki, K. Nakayama, E. Tsuji and Y. Aoki RSC Advances 2014, 4, 30927-30933.

[24] Efficient Growth of Anodic Films on Magnesium in Organic Electrolytes Containing Fluoride and Water
H. Habazaki, F. Kataoka, E. Tsuji and Y. Aoki Electrochem. Commun. 2014, 46, 30-32.

[23] Rapid Reduction of Titanium Dioxide Nano-particles by Reduction with a Calcium Reductant
T. Kikuchi, M. Yoshida, S. Matsuura, S. Natsui, E. Tsuji, H. Habazaki and R.O. Suzuki J. Phys. Chem. Solids 2014, 75, 1041-1048.

[22] Morphological Control of Anodic Crystalline TiO2 Nanochannel Films for Use in Size-selective Photocatalytic Decomposition of Organic Molecules
E. Tsuji, Y. Taguchi, Y. Aoki, T. Hashimoto. P. Skeldon, G. E. Thompson and H. Habazaki Appl. Sruf. Sci. 2014, 301, 500-507.

[21] Influence of Surface Roughening of Rutile Single Crystalline TiO2 on Photocatalytic Activity for Oxygen Photoevolution from Water in Acidic and Alkaline Solutions
E. Tsuji, K. Fukui and A. Imanishi J. Phys. Chem. C 2014, 118, 5406-5413.

[20] Highly Enhanced Corrosion Resistance of Stainless Steel by Sol-gel Layer-by-layer Aluminosilicate Thin Coatings from Diluted Precursor Solutions
H. Habazaki, T. Kimura, Y. Aoki, E. Tsuji and T. Yano J. Electrochem. Soc. 2014, 161, C57-C61.

[19] Formation and Dielectric Properties of Anodic Films Formed on Ta-W Alloys at Various Formation Voltages
M. Ishizuka, E. Tsuji, Y. Aoki and H. Habazaki Electrochemistry 2013, 81, 840-844.

[18] Compositional Dependence of the Proton Conductivity of Anodic ZrO2-WO3-SiO2 Nanofilms at Intermediate Temperatures
K. Ye, Y. Aoki, E. Tsuji, S. Nagata and H. Habazaki J. Electrochem. Soc. 2013, 160, F1096-F1102.

[17] Observation of Self-assembled Layers of Alkyl Phophonic Acid on Aluminium Using Low-voltage Scanning Electron Microscopy
H. Sato, T. Fujii, E. Tsuji, Y. Aoki K. Shimizu, P. Skeldon, G.E. Thompson and H. Habazaki Surf. Interface Anal. 2013, 45, 1441-1445.

[16] Preparation of Non-annealed Anatase TiO2 Film on ITO Substrate by Anodizing in Hot Phosphate/glycerol Electrolyte for Dye-sensitized Solar Cells
E. Tsuji, N. Hirata, Y. Aoki and H. Habazaki Mater. Lett. 2013, 91, 39-41.

[15] Important Role of Nanopore Morphology in Superoleophobic Hierarchical Surfaces
T. Fujii, E. Tsuji, Y. Aoki and H. Habazaki J. Phys. Chem.C 2012, 116, 23308-23314.

[14] Factors Influencing the Growth Behaviour of Nanoporous Anodic Films on Iron Under Galvanostatic Anodizing
Y. Konno, E. Tsuji, P. Skeldon, G.E. Thompson, H. Habazaki J. Solid State Electrochem. 2012, 16, 3887-3896.

[13] Photo-induced Properties of Non-annealed Anatase TiO2 Mesoporous Film Prepared by Anodizing in the Hot Phosphate/glycerol Electrolyte
Y. Taguchi, E. Tsuji, Y. Aoki and H. Habazaki Appl. Surf. Sci. 2012, 258, 9810-9815.

[12] Formation of Self-organized Nanoporous Anodic Films on Type 304 Stainless Steel
K. Kure, Y. Konno, E. Tsuji, P. Skeldon, G.E. Thompson and H. Habazaki Electrochem. Commun. 2012, 21, 1-4.

[11] Formation of Wear-resistant PEO Coatings on β-titanium Alloy at Low Electrolyte Temperatures
H. Habazaki, S. Tsunekawa, E. Tsuji and T. Nakayama Appl. Surf. Sci. 2012, 259, 711-718.

[10] Thickness Dependence of Proton Conductivity of Anodic ZrO2-WO3-SiO2 Nanofilms
Y. Ke, Y. Aoki, E. Tsuji, S. Nagata and H. Habazaki J. Power Sources 2012, 205, 194-200.

[9] Cathodic Pulse Breakdown of Anodic Films on Aluminum in Alkaline Silicate Electrolyte – Understanding the Role of Cathodic Half-cycle in AC Plasma Electrolytic Oxidation
S. P. Sah, E. Tsuji, Y. Aoki and H. Habazaki Corros. Sci. 2012, 55, 90-96.

[8] Growth and Field Crystallization of Anodic Films on Ta–Nb Alloys
S. Komiyama, E. Tsuji, Y. Aoki, H. Habazaki, M. Santamaria, F. Di Quarto, P. Skeldon and G. E. Thompson J. Solid State Electrochem. 2012, 16, 1595-1604.

[7] The Influence of Nitrogen Incorporation on the Optical Properties of Anodic Ta2O5
F. Di Franco, M. Santamaria, F. Di Quarto, E. Tsuji and H. Habazaki Electrochim. Acta 2012, 59, 382-386.

[6] In-situ MIR-IR Observation of Peroxo Species on Anatase TiO2 Particle during Oxygen Photoevolution Reaction
E. Tsuji, A. Imanishi and K. Fukui Electrochemistry 2011, 79, 787-789.

[5] Bistability in the Surface Dipole of Silicon Grafted with Copper Nanoparticles: An In-situ Electrochemical MIR-FTIR Study
K. Kamiya, E. Tsuji, A. Imanishi, K. Hashimoto and S. Nakanishi Electrochem. Commun. 2011, 13, 1447-1450.

[4] Improved Thermal Stability of Efficient Proton-Conducting Anodic ZrO2-WO3 Nanofilms by Incorporation of Silicon Species
K. Ye, Y. Aoki, E. Tsuji, S. Nagata and H. Habazaki J. Electrochem. Soc. 2011, 158, C385-C390.

[3] Electrocatalytic Activity of Amorphous RuO2 Electrode for Oxygen Evolution in an Aqueous Solution
E. Tsuji, A. Imanishi, K. Fukui and Y. Nakato Electrochim. Acta 2011, 56, 2009-2016.

[2] Ordered Nanogroove Arrays on n-TiO2 with a Variation of the Groove Depth, Formed by Self-Organized Photoetching
S. Nakanishi, T. Tanaka, Y. Saji, E. Tsuji, S. Fukushima, K. Fukami, T. Nagai, R. Nakamura, A. Imanishi and Y. Nakato J. Phys. Chem. C 2007, 111, 3934-3937.

[1] Dependence of the Work Function of TiO2 (Rutile) on Crystal Faces, Studied by a Scanning Auger Microprobe
A. Imanishi, E. Tsuji and Y. Nakato J. Phys. Chem. C 2007, 111, 2128-2132.


[ 国際会議論文 ]

[5] Formation of Self-Organized Porous Anodic Films on Iron and Stainless Steel
H. Habazaki, K. Shahzad, E. Tsuji and Y. Aoki ECS Transactions 2015, 69, 211-223.

[4] Fabrication of Super-oil-repellent Surfaces by Two-step Anodizing of Aluminum
H. Habazaki, T. Fujii, E. Tsuji and Y. Aoki ECS Transactions 2013, 50, 217-224.

[3] Influence of Yttrium Addition on the High Capacitance of ZrO2-SiO2 Nanocomposite Anodic Oxide Films
M. Ishizuka, E. Tsuji, Y. Aoki and H. Habazaki ECS Transactions 2013, 50, 245-254.

[2] Formation of Self-Organized Nanoporous Anodic Films on Carbon Steel
Y. Konno, E. Tsuji, Y. Aoki and H. Habazaki ECS Transactions 2013, 50, 183-190.

[1] High Proton Conductivity in Anodic ZrO2–WO3–SiO2 Nanofilms
Y. Ke, E. Tsuji, Y. Aoki and H. Habazaki ECS Transactions 2013, 50, 193-201.


[ 総説/解説 ]

[1] 陽極酸化ナノポーラス膜のエネルギーデバイスへの応用
辻悦司、幅崎浩樹、 静電気学会誌、2014、38、254-259.



【 関連リンク 】          片田研究室TOP           化学バイオ系学科HP           鳥取大学工学部HP